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A little bit about Chillicothe (From their wiki entry):

Chillicothe was the center of the old Hopewell tradition, which flourished from 200 BC until 500 AD This Amerindian culture had trade routes extending to the Rocky Mountains. They built mounds for ceremonial and burial purposes throughout the Scioto and Ohio River valleys. Later Native Americans who inhabited the area through the time of European contact included Shawnees.

It was after the American Revolution that most European settlement came to this area. Migrants from Virginia and Kentucky moved west along the Ohio River in search of land. Chillicothe served as the capital of Ohio from the beginning of statehood in 1803 until 1810 when Zanesville became the capital for two years. The capital was moved to Zanesville as part of a state legislative compromise to get a bill passed. In 1812 the legislature moved the capital back to Chillicothe. In 1816 the state legislature voted to move the capital again, to Columbus to have it near the geographic center of the state, where it would be more accessible to most citizens.

Migrants to Chillicothe included free blacks, who came to a place with fewer restrictions than in the slave states. They created a vibrant community in Chillicothe, where they aided runaway slaves coming north. As tensions increased prior to the breakout of the American Civil War, The free black community at Chillicothe became an important stop for refugees on the Underground Railroad. Slaves escaping from the South traveled across the Ohio River to freedom, and then up the Scioto River to get more distance from their former homes and slave hunters. White abolitionists aided the Underground Railroad as well.

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